Transformation of 2-allyl-1,3-diketones to bicyclic compounds containing 1,2-dioxolane and tetrahydrofuran rings using the I 2 /H 2 O 2 system Научная публикация
| Журнал |
Tetrahedron Letters
ISSN: 0040-4039 , E-ISSN: 1873-3581 |
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| Вых. Данные | Год: 2016, Том: 57, Номер: 8, Страницы: 949-952 Страниц : 4 DOI: 10.1016/j.tetlet.2016.01.061 | ||||||||
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Реферат:
A one-pot procedure was developed for the assembly of bicyclic compounds containing 1,2-dioxolane and tetrahydrofuran rings based on the reaction of 2-allyl-1,3-diketones with the I2/H2O2 system. A fivefold molar excess of H2O2 and a twofold excess of I2 are required for the selective formation of tetrahydrofurodioxoles. The synthesis of these structurally complex molecules is unusual in that it does not produce the expected bridged tetraoxanes, products of the addition of several H2O2 molecules to a carbonyl group, or the products of double bond iodoperoxidation.
Библиографическая ссылка:
Zdvizhkov A.T.
, Terent’ev A.O.
, Radulov P.S.
, Novikov R.A.
, Tafeenko V.A.
, Chernyshev V.V.
, Ilovaisky A.I.
, Levitsky D.O.
, Fleury F.
, Nikishin G.I.
Transformation of 2-allyl-1,3-diketones to bicyclic compounds containing 1,2-dioxolane and tetrahydrofuran rings using the I 2 /H 2 O 2 system
Tetrahedron Letters. 2016. V.57. N8. P.949-952. DOI: 10.1016/j.tetlet.2016.01.061 WOS Scopus OpenAlex
Transformation of 2-allyl-1,3-diketones to bicyclic compounds containing 1,2-dioxolane and tetrahydrofuran rings using the I 2 /H 2 O 2 system
Tetrahedron Letters. 2016. V.57. N8. P.949-952. DOI: 10.1016/j.tetlet.2016.01.061 WOS Scopus OpenAlex
Идентификаторы БД:
| Web of science: | WOS:000370307800028 |
| Scopus: | 2-s2.0-84955457218 |
| OpenAlex: | W2280890729 |