Coupling of gem -difluorinated organozinc reagents with S-electrophiles

Coupling of gem -difluorinated organozinc reagents with S-electrophiles Full article

Journal

Journal of Fluorine Chemistry
ISSN: 1873-3328 , E-ISSN: 0022-1139

Output data

Year: 2016, Volume: 191, Pages: 143-148 Pages count : 6 DOI: 10.1016/j.jfluchem.2016.07.018

Authors

Ashirbaev Salavat S. ^1,2 , Levin Vitalij V. ² , Struchkova Marina I. ² , Dilman Alexander D. ²

Affiliations

1	Moscow State University, Department of Chemistry, 119991 Moscow, Leninskie Gory 1-3, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, 119991 Moscow, Leninsky prosp. 47, Russian Federation

gem-Difluorinated organozinc reagents, which were prepared by insertion of CF2-fragment into Csingle bondZn bond, couple with diethyl dixanthogen, di(benzothiazolyl) disulfide, and tetraethylthiuram disulfide. The reaction is promoted either by a copper(I) catalyst or by irradiation with blue light in the presence of Eosin Y disodium salt.

Ashirbaev S.S. , Levin V.V. , Struchkova M.I. , Dilman A.D.
Coupling of gem -difluorinated organozinc reagents with S-electrophiles
Journal of Fluorine Chemistry. 2016. V.191. P.143-148. DOI: 10.1016/j.jfluchem.2016.07.018 WOS OpenAlex

Web of science:	WOS:000388058300018
OpenAlex:	W2494558547

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