Enthalpies of formation of 3,4- and 3,5-dinitro-1-trimethyl-1Н-pyrazoles

Enthalpies of formation of 3,4- and 3,5-dinitro-1-trimethyl-1Н-pyrazoles Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2016, Volume: 65, Number: 12, Pages: 2783-2788 Pages count : 6 DOI: 10.1007/s11172-016-1656-9

Authors

Kazakov A.I. ¹ , Dalinger I.L. ² , Zyuzin I.N. ¹ , Lempert D.B. ¹ , Plishkin N.A. ¹ , Sheremetev A.B. ²

Affiliations

1	Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432 Chernogolovka, Moscow Region, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation

The standard enthalpies of combustion and formation for isomeric polynitropyrazoles, viz., 3,4- and 3,5-dinitro-1-trinitromethyl-1Н-pyrazoles, were measured by combustion calorimetry in an oxygen atmosphere. The enthalpies of formation for the 3,4-dinitro isomer by 19.7 kJ mol–1 exceeds the corresponding parameter for the 3,5-isomer.

Kazakov A.I. , Dalinger I.L. , Zyuzin I.N. , Lempert D.B. , Plishkin N.A. , Sheremetev A.B.
Enthalpies of formation of 3,4- and 3,5-dinitro-1-trimethyl-1Н-pyrazoles
Russian Chemical Bulletin. 2016. V.65. N12. P.2783-2788. DOI: 10.1007/s11172-016-1656-9 WOS Scopus OpenAlex

≡ Web of science:	WOS:000402197500001
≡ Scopus:	2-s2.0-85019770502
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