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Supercritical fluids in chemistry Обзор

Журнал

Russian Chemical Reviews
ISSN: 1468-4837 , E-ISSN: 0036-021X

Вых. Данные

Год: 2020, Том: 89, Номер: 12, Страницы: 1337-1427 Страниц : 91 DOI: 10.1070/rcr4932

Авторы

Alekseev Evgenii S. ¹ , Alentiev Alexander Yu. ² , Belova Anastasia S. ³ , Bogdan Viktor I. ^1,4 , Bogdan Tatiana V. ¹ , Bystrova Aleksandra V. ^3,5 , Gafarova Elvira R. ⁶ , Golubeva Elena N. ¹ , Grebenik Ekaterina A. ⁶ , Gromov Oleg I. ¹ , Davankov Vadim A. ³ , Zlotin Sergei G. ⁴ , Kiselev Mikhail G. ⁷ , Koklin Aleksei E. ⁴ , Kononevich Yuriy N. ³ , Lazhko Alexey E. ⁸ , Lunin Valerii V. ¹ , Lyubimov Sergey E. ³ , Martyanov Oleg N. ⁹ , Mishanin Igor I. ⁴ , Muzafarov Aziz M. ^5,6 , Nesterov Nikolay S. ⁹ , Nikolaev Alexander Yu. ³ , Oparin Roman D. ⁷ , Parenago Olga O. ⁸ , Parenago Oleg P. ² , Pokusaeva Yana A. ⁴ , Ronova Inga A. ³ , Solovieva Anna B. ¹⁰ , Temnikov Maxim N. ³ , Timashev Peter S. ^7,10,11 , Turova Olga V. ⁴ , Filatova Evgeniya V. ⁴ , Philippov Alexey A. ⁹ , Chibiryaev A.M. ⁹ , Shalygin Anton S. ⁹

Организации

1	Lomonosov Moscow State University, Faculty of Chemistry, Leninskiye Gory, stroenie 3, 119991 Moscow, Russian Federation,
2	A.V.Topchiev Institute of Petrochemical Synthesis of the Russian Academy of Sciences, Leninsky prosp. 29, 119991 Moscow, Russian Federation,
3	A.N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, ul. Vavilova, 28, 119991 Moscow, Russian Federation
4	N.D.Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences, Leninsky prosp. 47, 119991 Moscow, Russian Federation,
5	Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences, ul. Profsoyuznaya 70, 117393 Moscow, Russian Federation,
6	I.M.Sechenov First Moscow State Medical University, Institute for Regenerative Medicine, ul. Trubetskaya 8, stroenie 2, 119991 Moscow, Russian Federation,
7	G.A.Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, ul. Akademicheskaya 1, 153045 Ivanovo, Russian Federation,
8	Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Leninsky prosp. 31, 119991 Moscow, Russian Federation
9	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, prosp. Akademika Lavrentieva 5, 630090 Novosibirsk, Russian Federation,
10	Semenov Institute of Chemical Physics of the Russian Academy of Sciences, ul. Kosygina 4, 117977 Moscow, Russian Federation,
11	Institute of Photonic Technologies, Federal Research Center ‘Crystallography and Photonics’ of the Russian Academy of Sciences, ul. Pionerskaya 2, 108840 Moscow, Troitsk, Russian Federation

This review analyzes the rapidly developing applications of supercritical fluids, mainly supercritical carbon dioxide, in catalysis, chemistry of high-molecular-weight compounds, and medicinal chemistry in Russia and abroad. It considers the methods of catalyst preparation based on impregnation of inorganic and organic supports with metal-containing compounds, immobilization of organometallic and metal complex reagents in matrices of oxide and polymer supports, and deposition processes employing supercritical fluids. An analysis is presented of the prospects for applying CO2 and some organic compounds, such as aliphatic alcohols, in sub- and supercritical states as reactants and (or) solvents for catalytic reactions of hydrocarbon isomerization and cracking, hydrogenation, dehydrogenation, oxidation, etc., including the asymmetric reactions. The review discusses processes of synthesizing and modifying polymer materials for various purposes, including aerogels, foams, and composites impregnated with photochromes, in a supercritical fluid medium. Special attention is paid to supercritical one-pot processes, which make the techniques of obtaining new materials simpler, less expensive, and more efficient. The work investigates the effect of supercritical CO2 on the morphology, gas separation characteristics, and dielectric properties of polymers. One of the promising applications of supercritical fluids in medicine is the use in transplantology and pharmacology, for example, for the preparation of drug polymorphs with higher bioavailability. The review also provides an overview of the recent data on the use of EPR spectroscopy for studying the properties of supercritical fluids, including those exhibited in the vicinity of the critical point and identifying the intermediates of chemical reactions in such media.

Alekseev E.S. , Alentiev A.Y. , Belova A.S. , Bogdan V.I. , Bogdan T.V. , Bystrova A.V. , Gafarova E.R. , Golubeva E.N. , Grebenik E.A. , Gromov O.I. , Davankov V.A. , Zlotin S.G. , Kiselev M.G. , Koklin A.E. , Kononevich Y.N. , Lazhko A.E. , Lunin V.V. , Lyubimov S.E. , Martyanov O.N. , Mishanin I.I. , Muzafarov A.M. , Nesterov N.S. , Nikolaev A.Y. , Oparin R.D. , Parenago O.O. , Parenago O.P. , Pokusaeva Y.A. , Ronova I.A. , Solovieva A.B. , Temnikov M.N. , Timashev P.S. , Turova O.V. , Filatova E.V. , Philippov A.A. , Chibiryaev A.M. , Shalygin A.S.
Supercritical fluids in chemistry
Russian Chemical Reviews. 2020. V.89. N12. P.1337-1427. DOI: 10.1070/rcr4932 WOS Scopus OpenAlex

Web of science:	WOS:000604750000001
Scopus:	2-s2.0-85097877755
OpenAlex:	W3091396021

БД	Цитирований
OpenAlex	91
Scopus	72
Web of science	76