Energetic Polymer Possessing Furazan, 1,2,3-Triazole, and Nitramine Subunits | Sciact

Energetic Polymer Possessing Furazan, 1,2,3-Triazole, and Nitramine Subunits Научная публикация

Журнал

International Journal of Molecular Sciences
ISSN: 1661-6596 , E-ISSN: 1422-0067

Вых. Данные

Год: 2023, Том: 24, Номер: 11, Номер статьи : 9645, Страниц : DOI: 10.3390/ijms24119645

Авторы

Gribov Pavel S. ¹ , Kondakova Natalia N. ² , Il’icheva Natalia N. ² , Stepanova Evgenia R. ² , Denisyuk Anatoly P. ² , Sizov Vladimir A. ² , Dotsenko Varvara D. ² , Vinogradov Dmitry B. ¹ , Bulatov Pavel V. ¹ , Sinditskii Valery P. ² , Suponitsky Kyrill Yu. ^3,4 , Il’in Mikhail M. ⁴ , Keshtov Mukhamed L. ⁴ , Sheremetev Aleksei B. ¹

Организации

1	Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prosp., Moscow 119991, Russia
2	Mendeleev University of Chemical Technology, 9 Miusskaya pl., Moscow 125047, Russia
3	Basic Department of Chemistry of Innovative Materials and Technologies, Plekhanov Russian University of Economics, 36 Stremyannyi Line, Moscow 117997, Russia
4	Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow 119991, Russia

A [3 + 2] cycloaddition reaction using dialkyne and diazide comonomers, both bearing explosophoric groups, to synthesize energetic polymers containing furazan and 1,2,3-triazole ring as well as nitramine group in the polymer chain have been described. The developed solvent- and catalyst-free approach is methodologically simple and effective, the comonomers used are easily available, and the resulting polymer does not need any purification. All this makes it a promising tool for the synthesis of energetic polymers. The protocol was utilized to generate multigram quantities of the target polymer, which has been comprehensively investigated. The resulting polymer was fully characterized by spectral and physico-chemical methods. Compatibility with energetic plasticizers, thermochemical characteristics, and combustion features indicate the prospects of this polymer as a binder base for energetic materials. The polymer of this study surpasses the benchmark energetic polymer, nitrocellulose (NC), in a number of properties.

Gribov P.S. , Kondakova N.N. , Il’icheva N.N. , Stepanova E.R. , Denisyuk A.P. , Sizov V.A. , Dotsenko V.D. , Vinogradov D.B. , Bulatov P.V. , Sinditskii V.P. , Suponitsky K.Y. , Il’in M.M. , Keshtov M.L. , Sheremetev A.B.
Energetic Polymer Possessing Furazan, 1,2,3-Triazole, and Nitramine Subunits
International Journal of Molecular Sciences. 2023. V.24. N11. 9645 . DOI: 10.3390/ijms24119645 WOS Scopus OpenAlex

≡ Web of science:	WOS:001003466100001
≡ Scopus:	2-s2.0-85161479298
≡ OpenAlex:	W4379231549