Lutetium Cyclopentadienyl Complex with the 2,6-Di-tert-Butylanthracene Dianion

Lutetium Cyclopentadienyl Complex with the 2,6-Di-tert-Butylanthracene Dianion Full article

Journal

Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318

Output data

Year: 2023, Volume: 49, Number: 6, Pages: 369-376 Pages count : 8 DOI: 10.1134/s1070328423700586

Authors

Roitershtein D.M. ¹ , Lyssenko K.A. ² , Nifant’ev I.E. ^1,2,3 , Minyaev M.E. ³

Affiliations

1	Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia
2	Moscow State University, Moscow, Russia
3	Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia

The reaction of 2,6-di(tert-butyl)anthracene with potassium graphite and monocyclopentadienyllutetium dichloride tetrahydrofuranate in THF gave the anthracenide complex [(η5-C5H5)Lu(η2-2,6-tBu2C14H8)(THF)2] (I), which was studied by X-ray diffraction (CCDC no. 2215512). Complex I crystallizes in the orthorhombic space group P212121. The structural rigidity of the Lu(O)2Cp(anthracene) crystallographic node was demonstrated. The retention of the structure of complex I in solution was confirmed by NMR techniques.

Roitershtein D.M. , Lyssenko K.A. , Nifant’ev I.E. , Minyaev M.E.
Lutetium Cyclopentadienyl Complex with the 2,6-Di-tert-Butylanthracene Dianion
Russian Journal of Coordination Chemistry. 2023. V.49. N6. P.369-376. DOI: 10.1134/s1070328423700586 WOS Scopus OpenAlex

≡ Web of science:	WOS:001020623500007
≡ Scopus:	2-s2.0-85163360723
≡ OpenAlex:	W4382045129