Unusual transformation of 3-alkylfuroxans into 3-(nitrooxyalkyl)furoxans on treatment with a mixture of nitric and sulfuric acids

Unusual transformation of 3-alkylfuroxans into 3-(nitrooxyalkyl)furoxans on treatment with a mixture of nitric and sulfuric acids Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2016, Volume: 65, Number: 12, Pages: 2901-2906 Pages count : 6 DOI: 10.1007/s11172-016-1675-6

Authors

Ogurtsov V.A. ¹ , Shastin A.V. ² , Zlotin S.G. ¹ , Rakitin O.A. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
2	Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation

A versatile one-pot synthesis of 4-substituted 3-(nitrooxyalkyl)furoxans by the reaction of 3-alkylfuroxans with a mixture of nitric and sulfuric acids was developed. A plausible mechanism of this unusual transformation was explained in terms of a new Grob-type fragmentation.

Ogurtsov V.A. , Shastin A.V. , Zlotin S.G. , Rakitin O.A.
Unusual transformation of 3-alkylfuroxans into 3-(nitrooxyalkyl)furoxans on treatment with a mixture of nitric and sulfuric acids
Russian Chemical Bulletin. 2016. V.65. N12. P.2901-2906. DOI: 10.1007/s11172-016-1675-6 WOS Scopus OpenAlex

Web of science:	WOS:000402197500020
Scopus:	2-s2.0-85019665758
OpenAlex:	W2619182568

DB	Citing
OpenAlex	2
Scopus	2
Web of science	2