Novel highly energetic pyrazoles: N-fluorodinitromethyl and N-[(difluoroamino)dinitromethyl] derivatives

Novel highly energetic pyrazoles: N-fluorodinitromethyl and N-[(difluoroamino)dinitromethyl] derivatives Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2015, Volume: 25, Number: 6, Pages: 429-431 Pages count : 3 DOI: 10.1016/j.mencom.2015.11.010

Authors

Dalinger Igor L. ¹ , Shakhnes Aleksandr Kh. ¹ , Monogarov Konstantin A. ² , Suponitsky Kyrill Yu. ³ , Sheremetev Aleksei B. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
2	N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 119991 Moscow, Russian Federation
3	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991 Moscow, Russian Federation

Treatment of 1,1-dinitro-1-(3,5-dinitropyrazol-1-yl)methanide with electrophilic fluorinating or difluoroaminating agents affords the corresponding fluorodinitromethyl or (difluoroamino)dinitromethyl pyrazole derivatives. Single crystal X-ray diffraction analysis shows a remarkable high density and DSC exhibits acceptable thermal stability of the compounds.

Dalinger I.L. , Shakhnes A.K. , Monogarov K.A. , Suponitsky K.Y. , Sheremetev A.B.
Novel highly energetic pyrazoles: N-fluorodinitromethyl and N-[(difluoroamino)dinitromethyl] derivatives
Mendeleev Communications. 2015. V.25. N6. P.429-431. DOI: 10.1016/j.mencom.2015.11.010 WOS Scopus Scopus OpenAlex

≡ Web of science:	WOS:000367761800010
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