Реферат: Properties of Pd–Cu/Al2O3 catalysts prepared using PdCu(CH3CO2)4 acetate heteronuclear complexes as precursors in the liquid-phase diphenylacetylene (DPA) hydrogenation have been studied. It has been established that the reaction over the Pd–Cu/Al2O3 catalyst proceeds more selectively than over the commercial Lindlar catalyst; in addition, high activity is achieved at a substantially lower palladium content. The maximum selectivity of DPA hydrogenation is observed with the catalyst reduced in a hydrogen atmosphere without any intermediate calcination that can result in the destruction of the bimetallic acetate complex. FTIR spectroscopy data for adsorbed CO show that the high selectivity of hydrogenation is due to the formation of homogeneous Pd–Cu particles and to the absence of monometallic palladium particles. This can be explained by the retention of the initial complex structure at all of the catalyst preparation stages until the formation of bimetallic particles during hydrogenation.

Библиографическая ссылка: Markov P.V. , Bragina G.O. , Baeva G.N. , Tkachenko O.P. , Mashkovsky I.S. , Yakushev I.A. , Kozitsyna N.Y. , Vargaftik M.N. , Stakheev A.Y.
Pd–Cu catalysts from acetate complexes in liquid-phase diphenylacetylene hydrogenation
Kinetics and Catalysis. 2015. V.56. N5. P.591-597. DOI: 10.1134/s0023158415050122 WOS Scopus OpenAlex

Идентификаторы БД:

Web of science:	WOS:000361757300005
Scopus:	2-s2.0-84942588515
OpenAlex:	W1920699699

Цитирование в БД:

БД	Цитирований
OpenAlex	31
Scopus	29
Web of science	30

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