Reduction of carbon dioxide by hydrogen on metal–carbon catalysts under supercritical conditions

Reduction of carbon dioxide by hydrogen on metal–carbon catalysts under supercritical conditions Full article

Journal

Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X

Output data

Year: 2016, Volume: 90, Number: 12, Pages: 2352-2357 Pages count : 6 DOI: 10.1134/s0036024416120050

Authors

Bogdan V.I. ^1,2 , Koklin A.E. ¹ , Kozak D.O. ¹ , Kustov L.M. ^2,1

Affiliations

1	Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991 Russia
2	Department of Chemistry, Moscow State University, Moscow, 119991 Russia

The reduction of carbon dioxide with hydrogen on metal–carbon (Ru, Rh, Ir) catalysts is investigated under supercritical conditions for the first time. High selectivity (close to 100%) toward methanation with good stability of catalytic activity is observed for Ru- and Rh-containing catalyst, while the preferred reduction to CO is observed for Ir/C catalyst.

Bogdan V.I. , Koklin A.E. , Kozak D.O. , Kustov L.M.
Reduction of carbon dioxide by hydrogen on metal–carbon catalysts under supercritical conditions
Russian Journal of Physical Chemistry A. 2016. V.90. N12. P.2352-2357. DOI: 10.1134/s0036024416120050 WOS Scopus OpenAlex

≡ Web of science:	WOS:000387416500005
≡ Scopus:	2-s2.0-85013829886
≡ OpenAlex:	W2547513846