Reactions of chloromethoxy-substituted 3-(2-acetoxyethyl)-1-hydroxytriaz-1-ene 2-oxides with 1-alkoxy-3-(2-hydroxyethyl)triaz-1-ene 2-oxide alkali salts

Reactions of chloromethoxy-substituted 3-(2-acetoxyethyl)-1-hydroxytriaz-1-ene 2-oxides with 1-alkoxy-3-(2-hydroxyethyl)triaz-1-ene 2-oxide alkali salts Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2016, Volume: 65, Number: 12, Pages: 2879-2886 Pages count : 8 DOI: 10.1007/s11172-016-1672-9

Authors

Smirnov G.A. ¹ , Gordeev P.B. ¹ , Nikitin S.V. ¹ , Pokhvisneva G.V. ¹ , Ternikova T.V. ¹ , Luk’yanov O.A. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation

Reactions of 1-alkoxy-3-(2-hydroxyethyl)triaz-1-ene 2-oxides and 1-chloromethoxytriaz1-ene 2-oxides with chloromethoxy derivatives of 3-alkyl-3-(2-acetoxyethyl)- and 3,3-bis(2-acetoxyethyl)-1-hydroxytriaz-1-ene 2-oxides result in very complex product mixtures with the major product comprising the starting salt fragments linked by a methylene bridge. In these products, the central methylene group bridges either two oxygen atoms or two nitrogen atoms, or one oxygen and one nitrogen atom. The synthesized compounds contain from two to four 2-hydroxyethyl moieties.

Smirnov G.A. , Gordeev P.B. , Nikitin S.V. , Pokhvisneva G.V. , Ternikova T.V. , Luk’yanov O.A.
Reactions of chloromethoxy-substituted 3-(2-acetoxyethyl)-1-hydroxytriaz-1-ene 2-oxides with 1-alkoxy-3-(2-hydroxyethyl)triaz-1-ene 2-oxide alkali salts
Russian Chemical Bulletin. 2016. V.65. N12. P.2879-2886. DOI: 10.1007/s11172-016-1672-9 WOS Scopus OpenAlex

≡ Web of science:	WOS:000402197500017
≡ Scopus:	2-s2.0-85019722187
≡ OpenAlex:	W2619584296