Kinetics and mechanism of the electrochemical reduction of [1,2-bis(tert-butylperoxy)ethyl]benzene under conditions of the in situ recovery of a platinum surface

Kinetics and mechanism of the electrochemical reduction of [1,2-bis(tert-butylperoxy)ethyl]benzene under conditions of the in situ recovery of a platinum surface Full article

Journal

Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X

Output data

Year: 2016, Volume: 90, Number: 2, Pages: 475-478 Pages count : 4 DOI: 10.1134/s0036024416020333

Authors

Vedenyapina M.D. ^1,3 , Sharipov M.Yu. ^1,4 , Terent’ev A.O. ^1,4 , Skundin A.M. ² , Vedenyapin A.A. ^1,3

Affiliations

1	Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991 Russia
2	Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, 119071 Russia
3	Moscow Technological Institute, Moscow, 117292 Russia
4	Mendeleev University of Chemical Technology, Moscow, 125047 Russia

The behavior of [1,2-bis(tert-butylperoxy)ethyl]benzene (I) on Pt electrode is studied by means of cyclic voltammetry (CVA). A comparison of the electrochemical properties of I and the properties of previously studied bridge-type 1,2,4,5-tetraoxane ((1,4)-1,4-dimethyl-7-(4-methylbenzyl)-2,3,5,6-tetraoxabicyclo[2.2.1]heptane) (II) shows that the biperoxide studied in this work is reduced on a Pt electrode at lower cathodic potentials and is resistant to electrooxidation.

Vedenyapina M.D. , Sharipov M.Y. , Terent’ev A.O. , Skundin A.M. , Vedenyapin A.A.
Kinetics and mechanism of the electrochemical reduction of [1,2-bis(tert-butylperoxy)ethyl]benzene under conditions of the in situ recovery of a platinum surface
Russian Journal of Physical Chemistry A. 2016. V.90. N2. P.475-478. DOI: 10.1134/s0036024416020333 WOS Scopus OpenAlex

Web of science:	WOS:000368190500036
Scopus:	2-s2.0-84953439635
OpenAlex:	W2463364304

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