Peroxidation of β-diketones and β-keto esters with tert-butyl hydroperoxide in the presence of Cu(ClO4)2/SiO2

Peroxidation of β-diketones and β-keto esters with tert-butyl hydroperoxide in the presence of Cu(ClO4)2/SiO2 Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2014, Volume: 63, Number: 11, Pages: 2461-2466 Pages count : 6 DOI: 10.1007/s11172-014-0763-8

Authors

Terent´ev A.O. ¹ , Vil V.A. ¹ , Bityukov O.V. ¹ , Nikishin G.I. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Reactions of β-diketones and β-keto esters with tert-butyl hydroperoxide under heterogeneous conditions using SiO2-supported copper(II) perchlorate as a catalyst give rise to α-peroxidation products in 65—82% yields. A possibility to reuse the catalyst was demonstrated.

Terent´ev A.O. , Vil V.A. , Bityukov O.V. , Nikishin G.I.
Peroxidation of β-diketones and β-keto esters with tert-butyl hydroperoxide in the presence of Cu(ClO4)2/SiO2
Russian Chemical Bulletin. 2014. V.63. N11. P.2461-2466. DOI: 10.1007/s11172-014-0763-8 WOS Scopus OpenAlex

≡ Web of science:	WOS:000357684400008
≡ Scopus:	2-s2.0-84937791752
≡ OpenAlex:	W975646459