Kinetics and mechanism of N-chloromethylamine decomposition in solutions

Kinetics and mechanism of N-chloromethylamine decomposition in solutions Full article

Journal

Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X

Output data

Year: 2016, Volume: 90, Number: 3, Pages: 541-544 Pages count : 4 DOI: 10.1134/s0036024416030225

Authors

Kuznetsov V.V. ¹ , Vedenyapina M.D. ^1,2 , Pleshchev M.I. ¹ , Gashev S.B. ¹ , Makhova N.N. ¹ , Vedenyapin A.A. ^1,2

Affiliations

1	Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991 Russia
2	Moscow Technological Institute, Moscow, 117292 Russia

Kinetics of N-chloromethylamine decomposition in an aqueous base medium and chloroform at different temperatures is studied. The decomposition of N-chloromethylamine is found to obey a second order equation in an aqueous base medium at an equimolar ratio of the reagents and a first order equation in chloroform with excess base. The activation energy of N-chloromethylamine decomposition in the both solvents is determined. A mechanism for the reaction is proposed. N-Chloromethylamine is shown to have approximately equal stability in these solvents within the studied temperature range.

Kuznetsov V.V. , Vedenyapina M.D. , Pleshchev M.I. , Gashev S.B. , Makhova N.N. , Vedenyapin A.A.
Kinetics and mechanism of N-chloromethylamine decomposition in solutions
Russian Journal of Physical Chemistry A. 2016. V.90. N3. P.541-544. DOI: 10.1134/s0036024416030225 WOS Scopus OpenAlex

Web of science:	WOS:000370798400005
Scopus:	2-s2.0-84958794133
OpenAlex:	W2302454228

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