GaCl3-Mediated Isomerization of Donor–Acceptor Cyclopropanes into (2-Arylalkylidene)malonates

GaCl3-Mediated Isomerization of Donor–Acceptor Cyclopropanes into (2-Arylalkylidene)malonates Full article

Journal

Synlett
ISSN: 0936-5214 , E-ISSN: 1437-2096

Output data

Year: 2016, Volume: 27, Number: 09, Pages: 1367-1370 Pages count : 4 DOI: 10.1055/s-0035-1561389

Authors

Novikov Roman A. ¹ , Tarasova Anna V. ¹ , Tomilov Yury V. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

A new process for isomerization of donor–acceptor cyclopropanes (2-arylcyclopropanedicarboxylates) by treatment with anhydrous gallium trichloride to give (2-arylalkylidene)malonates in high yields and with good selectivity has been developed. The reaction involves initial formation of a 1,2-dipolar gallium complex.

Novikov R.A. , Tarasova A.V. , Tomilov Y.V.
GaCl3-Mediated Isomerization of Donor–Acceptor Cyclopropanes into (2-Arylalkylidene)malonates
Synlett. 2016. V.27. N09. P.1367-1370. DOI: 10.1055/s-0035-1561389 WOS Scopus OpenAlex

≡ Web of science:	WOS:000376689000012
≡ Scopus:	2-s2.0-84960145489
≡ OpenAlex:	W2524475236