Electrochemically Induced Synthesis of Sulfonylated N-Unsubstituted Enamines from Vinyl Azides and Sulfonyl Hydrazides Full article
Journal |
Organic Letters
ISSN: 1523-7060 , E-ISSN: 1523-7052 |
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Output data | Year: 2020, Volume: 22, Number: 5, Pages: 1818-1824 Pages count : 7 DOI: 10.1021/acs.orglett.0c00139 | ||||
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Abstract:
Sulfonylated N-unsubstituted enamines were synthesized through a chain of chemical and electrochemical transformations via sulfonylation of vinyl azides. The disclosing of the N-unsubstituted enamines synthesis was based on a unique property of the azido group, which is its ability to eliminate the N2 molecule. Furthermore, a formal paradox is observed: a double bond reacts and a double bond is retained. Electrosynthesis proceeded in an undivided cell equipped with a graphite anode and a stainless steel cathode; NH4I was used as a supporting electrolyte.
Cite:
Mulina O.M.
, Zhironkina N.V.
, Paveliev S.A.
, Demchuk D.V.
, Terent’ev A.O.
Electrochemically Induced Synthesis of Sulfonylated N-Unsubstituted Enamines from Vinyl Azides and Sulfonyl Hydrazides
Organic Letters. 2020. V.22. N5. P.1818-1824. DOI: 10.1021/acs.orglett.0c00139 WOS Scopus OpenAlex
Electrochemically Induced Synthesis of Sulfonylated N-Unsubstituted Enamines from Vinyl Azides and Sulfonyl Hydrazides
Organic Letters. 2020. V.22. N5. P.1818-1824. DOI: 10.1021/acs.orglett.0c00139 WOS Scopus OpenAlex
Identifiers:
Web of science: | WOS:000518875500025 |
Scopus: | 2-s2.0-85080085909 |
OpenAlex: | W3007465111 |