Pd–Cu catalyst prepared from heterobimetallic PdCu2(OAc)6: an XRD-EXAFS study and activity/selectivity in the liquid-phase hydrogenation of a C≡C bond

Pd–Cu catalyst prepared from heterobimetallic PdCu2(OAc)6: an XRD-EXAFS study and activity/selectivity in the liquid-phase hydrogenation of a C≡C bond Научная публикация

Журнал

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Вых. Данные

Год: 2016, Том: 26, Номер: 6, Страницы: 502-504 Страниц : 3 DOI: 10.1016/j.mencom.2016.11.014

Авторы

Markov Pavel V. ¹ , Bragina Galina O. ¹ , Rassolov Aleksandr V. ¹ , Baeva Galina N. ¹ , Mashkovsky Igor S. ¹ , Murzin Vadim Yu. ² , Zubavichus Yan V. ² , Stakheev Aleksandr Yu. ¹

Организации

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
2	National Research Centre ‘Kurchatov Institute’, 123182 Moscow, Russian Federation

The formation of a PdCu alloy with an fcc structure in 1% Pd–1.2% Cu2 /Al2O3 (as evidenced by XRD and EXAFS data) significantly improves catalyst selectivity in the semihydrogenation of internal and terminal alkynes, which makes 1% Pd–1.2% Cu2 /Al2O3 a promising alternative to the commercial Lindlar catalyst.

Markov P.V. , Bragina G.O. , Rassolov A.V. , Baeva G.N. , Mashkovsky I.S. , Murzin V.Y. , Zubavichus Y.V. , Stakheev A.Y.
Pd–Cu catalyst prepared from heterobimetallic PdCu2(OAc)6: an XRD-EXAFS study and activity/selectivity in the liquid-phase hydrogenation of a C≡C bond
Mendeleev Communications. 2016. V.26. N6. P.502-504. DOI: 10.1016/j.mencom.2016.11.014 WOS Scopus OpenAlex

Web of science:	WOS:000390515200014
Scopus:	2-s2.0-84997501275
OpenAlex:	W2556342852

БД	Цитирований
OpenAlex	28
Scopus	27
Web of science	26