Preparation of catalysts for the Fischer–Tropsch synthesis by the deposition of cobalt reduced with NaBH4 onto a support

Preparation of catalysts for the Fischer–Tropsch synthesis by the deposition of cobalt reduced with NaBH4 onto a support Full article

Journal

Kinetics and Catalysis
ISSN: 1608-3210 , E-ISSN: 0023-1584

Output data

Year: 2015, Volume: 56, Number: 5, Pages: 625-630 Pages count : 6 DOI: 10.1134/s0023158415050043

Authors

Eliseev O.L. ¹ , Kamorin M.A. ¹ , Davydov P.E. ¹ , Volkov A.S. ¹ , Kazakov A.V. ¹ , Lapidus A.L. ¹

Affiliations

1	Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia

A new method for the preparation of catalysts for the Fischer–Tropsch synthesis is proposed; it consists in the deposition of cobalt metal on a support at the instant of reduction from salts with a solution of NaBH4. The catalysts thus prepared are stable in air, and they do not require further high-temperature activation by hydrogen. The specific rate of CO conversion was 3.4–3.7 molCO mol-1 Co h–1; the selectivity for higher hydrocarbons was up to 88 mol %, and the hydrocarbon chain growth index α was up to 0.87.

Eliseev O.L. , Kamorin M.A. , Davydov P.E. , Volkov A.S. , Kazakov A.V. , Lapidus A.L.
Preparation of catalysts for the Fischer–Tropsch synthesis by the deposition of cobalt reduced with NaBH4 onto a support
Kinetics and Catalysis. 2015. V.56. N5. P.625-630. DOI: 10.1134/s0023158415050043 WOS Scopus OpenAlex

Web of science:	WOS:000361757300009
Scopus:	2-s2.0-84942573628
OpenAlex:	W2483256072

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OpenAlex	4
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