Hepta(methoxycarbonyl)cycloheptatriene halo derivatives

Hepta(methoxycarbonyl)cycloheptatriene halo derivatives Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2015, Volume: 64, Number: 1, Pages: 241-245 Pages count : 5 DOI: 10.1007/s11172-015-0851-4

Authors

Platonov D.N. ¹ , Okonnishnikova G.P. ¹ , Levina A.A. ¹ , Tomilov Yu.V. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

A reaction of potassium hepta(methoxycarbonyl)cycloheptatrienide with chlorine and bromine gave high yields of the corresponding chloroand bromohepta(methoxycarbonyl)cycloheptatrienes; the fluoro derivative was obtained by the exchange reaction of the corresponding bromide with silver fluoride. In contrast to the mentioned halides, the iodo derivative has proved unstable. Thermolysis of bromohepta(methoxycarbonyl)cycloheptatriene was studied, as well as its conversion to the azido and methoxy derivatives upon treatment with NaN3 or methanol.

Platonov D.N. , Okonnishnikova G.P. , Levina A.A. , Tomilov Y.V.
Hepta(methoxycarbonyl)cycloheptatriene halo derivatives
Russian Chemical Bulletin. 2015. V.64. N1. P.241-245. DOI: 10.1007/s11172-015-0851-4 WOS Scopus OpenAlex

≡ Web of science:	WOS:000361494300040
≡ Scopus:	2-s2.0-84942081270
≡ OpenAlex:	W2274592519