Novel catalysts for selective hydrogenation of C≡C bond based on Pd nanoparticles immobilized in phenylenecarboxylate frameworks (NH2)-MIL-53(Al)

Novel catalysts for selective hydrogenation of C≡C bond based on Pd nanoparticles immobilized in phenylenecarboxylate frameworks (NH2)-MIL-53(Al) Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2015, Volume: 64, Number: 2, Pages: 284-290 Pages count : 7 DOI: 10.1007/s11172-015-0858-x

Authors

Stakheev A.Yu. ¹ , Isaeva V.I. ¹ , Markov P.V. ¹ , Turova O.V. ¹ , Mashkovskii I.S. ¹ , Kapustin G.I. ¹ , Saifutdinov B.R. ² , Kustov L.M. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation
2	Samara State Technical University, 244 ul. Molodogvardeiskaya, 443100, Samara, Russian Federation

Novel catalysts based on Pd nanoparticles encapsulated into microporous metal-organic framework MIL-53(Al) and NH2-MIL-53(Al) were synthesized. Their catalytic properties were studied in the model reaction of liquid-phase hydrogenation of diphenylacetylene (DPA) (293 K, = 5 atm). The activity and selectively of the palladium-containing materials Pd—MIL in DPA hydrogenation depend substantially on the nature of the organic linker.

Stakheev A.Y. , Isaeva V.I. , Markov P.V. , Turova O.V. , Mashkovskii I.S. , Kapustin G.I. , Saifutdinov B.R. , Kustov L.M.
Novel catalysts for selective hydrogenation of C≡C bond based on Pd nanoparticles immobilized in phenylenecarboxylate frameworks (NH2)-MIL-53(Al)
Russian Chemical Bulletin. 2015. V.64. N2. P.284-290. DOI: 10.1007/s11172-015-0858-x WOS Scopus OpenAlex

Web of science:	WOS:000363260900003
Scopus:	2-s2.0-84945182343
OpenAlex:	W2138216515

DB	Citing
OpenAlex	12
Scopus	11
Web of science	11