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Asymmetric aldol reactions in ketone/ketone systems catalyzed by ionic liquid-supported C2-symmetrical organocatalyst Full article

Journal Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436
Output data Year: 2015, Volume: 25, Number: 3, Pages: 168-170 Pages count : 3 DOI: 10.1016/j.mencom.2015.05.002
Authors Kochetkov Sergei V. 1 , Kucherenko Alexander S. 1 , Zlotin Sergei G. 1
Affiliations
1 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

Abstract: Ionic liquid-supported (1S,2S)- and (1R,2R)-1,2-bis[(S)-prolinamido]-1,2-diphenylethanes act as organocatalysts in asymmetric aldol reactions of acetone with α-keto esters or trifluoroacetophenone providing high yields and from moderate to high enantioselectivity. Recycling of the catalyst with a gradual decrease in conversion and ee values is possible.
Cite: Kochetkov S.V. , Kucherenko A.S. , Zlotin S.G.
Asymmetric aldol reactions in ketone/ketone systems catalyzed by ionic liquid-supported C2-symmetrical organocatalyst
Mendeleev Communications. 2015. V.25. N3. P.168-170. DOI: 10.1016/j.mencom.2015.05.002 WOS Scopus OpenAlex
Identifiers:
Web of science: WOS:000357142000002
Scopus: 2-s2.0-84930948086
OpenAlex: W973471862
Citing:
DB Citing
OpenAlex 19
Scopus 23
Web of science 24
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