Synthesis of tris(β,β,γ-oximinoalkyl)amines from aliphatic nitro compounds and methyl vinyl ketone

Synthesis of tris(β,β,γ-oximinoalkyl)amines from aliphatic nitro compounds and methyl vinyl ketone Full article

Journal

Tetrahedron Letters
ISSN: 0040-4039 , E-ISSN: 1873-3581

Output data

Year: 2014, Volume: 55, Number: 6, Pages: 1222-1225 Pages count : 4 DOI: 10.1016/j.tetlet.2014.01.003

Authors

Shalamova Elena A. ¹ , Lee Yeosan ² , Chung Garam ² , Semakin Artem N. ^1,3 , Oh Jinho ² , Sukhorukov Alexey Yu. ³ , Arkhipov Dmitry E. ⁴ , Ioffe Sema L. ^1,3 , Semenov Sergey E. ³

Affiliations

1	Moscow Chemical Lyceum, Tamozhenniy proezd 4, 111033 Moscow, Russia
2	Korea Science Academy of KAIST, 105-47, Baegyanggwanmun-ro, Busanjin-gu, 614-822 Busan, Republic of Korea
3	N.D. Zelinsky Institute of Organic Chemistry, Leninsky prospekt, 47, 119991 Moscow, Russia
4	A.N. Nesmeyanov Institute of Organic Chemistry, Vavilova St. 28, 119991 Moscow, Russia

A general strategy for the assembly of previously unknown tris(β,β,γ-oximinoalkyl)amines from aliphatic nitro compounds and methyl vinyl ketone is described. The strategy involves N,N-bis(siloxy)enamines as key intermediates. The latter are accessible by double silylation of alkylnitro compounds. Nickel(II) and copper(II) complexes of tris(β,β,γ-oximinoalkyl)amines are prepared and structurally characterized.

Shalamova E.A. , Lee Y. , Chung G. , Semakin A.N. , Oh J. , Sukhorukov A.Y. , Arkhipov D.E. , Ioffe S.L. , Semenov S.E.
Synthesis of tris(β,β,γ-oximinoalkyl)amines from aliphatic nitro compounds and methyl vinyl ketone
Tetrahedron Letters. 2014. V.55. N6. P.1222-1225. DOI: 10.1016/j.tetlet.2014.01.003 WOS Scopus OpenAlex

Web of science:	WOS:000331428400024
Scopus:	2-s2.0-84894998720
OpenAlex:	W2024381696

DB	Citing
OpenAlex	5
Scopus	7
Web of science	7