Dual Acridine/Decatungstate Photocatalysis for the Decarboxylative Radical Addition of Carboxylic Acids to Azomethines

Dual Acridine/Decatungstate Photocatalysis for the Decarboxylative Radical Addition of Carboxylic Acids to Azomethines Full article

Journal

Organic Letters
ISSN: 1523-7060 , E-ISSN: 1523-7052

Output data

Year: 2024, Volume: 26, Number: 15, Pages: 3174-3178 Pages count : 5 DOI: 10.1021/acs.orglett.4c00778

Authors

Rubanov Zakhar M. ¹ , Levin Vitalij V. ¹ , Dilman Alexander D. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Leninsky prosp. 47, 119991 Moscow, Russian Federation

A concept for the dual use of acridine and tetrabutylammonium decatungstate photocatalysts in the reactions of carboxylic acids is proposed. Imines generated in situ from aldehydes and p-methoxyaniline, as well as other azomethines, were used as radical acceptors. The role of the decatungstate is believed to facilitate the turnover of the acridine photocatalyst by means of hydrogen atom transfer.

Rubanov Z.M. , Levin V.V. , Dilman A.D.
Dual Acridine/Decatungstate Photocatalysis for the Decarboxylative Radical Addition of Carboxylic Acids to Azomethines
Organic Letters. 2024. V.26. N15. P.3174-3178. DOI: 10.1021/acs.orglett.4c00778 WOS Scopus OpenAlex

Web of science:	WOS:001200653300001
Scopus:	2-s2.0-85189975472
OpenAlex:	W4394568107

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OpenAlex	8
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