Partial oxidation of toluene with nitrous oxide under supercritical conditions

Partial oxidation of toluene with nitrous oxide under supercritical conditions Full article

Journal

Kinetics and Catalysis
ISSN: 1608-3210 , E-ISSN: 0023-1584

Output data

Year: 2014, Volume: 55, Number: 1, Pages: 93-96 Pages count : 4 DOI: 10.1134/s0023158414010066

Authors

Kustov A.L. ¹ , Benavente Donaire P.S. ¹ , Koklin A.E. ¹ , Bogdan V.I. ^1,2

Affiliations

1	Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia
2	Faculty of Chemistry, Moscow State University, Moscow, 119991 Russia

The partial oxidation of toluene with nitrous oxide over the H-ZSM-5 catalyst under supercritical conditions at temperatures of 370–420°C and pressures of 70–160 atm has been investigated for the first time. The maximum cresol selectivity under these conditions is 32%. The amounts of the resulting cresol isomers form the following decreasing sequence: m-cresol > o-cresol > p-cresol. The partial oxidation of toluene is accompanied by disproportionation and biphenyl formation.

Kustov A.L. , Benavente Donaire P.S. , Koklin A.E. , Bogdan V.I.
Partial oxidation of toluene with nitrous oxide under supercritical conditions
Kinetics and Catalysis. 2014. V.55. N1. P.93-96. DOI: 10.1134/s0023158414010066 WOS Scopus OpenAlex

≡ Web of science:	WOS:000332333700013
≡ Scopus:	2-s2.0-84897814426
≡ OpenAlex:	W2053194195