Supported catalysts based on Pd–In nanoparticles for the liquid-phase hydrogenation of terminal and internal alkynes: 1. formation and structure Научная публикация
| Журнал |
Kinetics and Catalysis
ISSN: 1608-3210 , E-ISSN: 0023-1584 |
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| Вых. Данные | Год: 2016, Том: 57, Номер: 5, Страницы: 617-624 Страниц : 8 DOI: 10.1134/s002315841605013x | ||||
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Реферат:
The formation of Pd–In catalysts synthesized from the heteronuclear acetate complex PdIn(CH3COO)5 was studied by temperature-programmed reduction, electron microscopy, IR spectroscopy of adsorbed CO and hydrogen temperature-programmed desorption (H2-TPD). IR spectroscopy of adsorbed CO and H2-TPD confirmed the formation of bimetallic Pd–In nanoparticles. It was found that the Pd–In nanoparticle surface contains predominantly Pd atoms separated from one another by indium atoms, which is evidenced by the disappearance of the CO band shift resulting from the lateral dipole–dipole interaction between adsorbed CO molecules and by a significant decrease in the band intensity of CO adsorbed in bridged form. Almost complete inhibition of palladium hydride (PdHx) provides additional evidence of the formation of Pd–In bimetallic particles.
Библиографическая ссылка:
Markov P.V.
, Bragina G.O.
, Baeva G.N.
, Tkachenko O.P.
, Mashkovskii I.S.
, Yakushev I.A.
, Vargaftik M.N.
, Stakheev A.Y.
Supported catalysts based on Pd–In nanoparticles for the liquid-phase hydrogenation of terminal and internal alkynes: 1. formation and structure
Kinetics and Catalysis. 2016. V.57. N5. P.617-624. DOI: 10.1134/s002315841605013x WOS OpenAlex
Supported catalysts based on Pd–In nanoparticles for the liquid-phase hydrogenation of terminal and internal alkynes: 1. formation and structure
Kinetics and Catalysis. 2016. V.57. N5. P.617-624. DOI: 10.1134/s002315841605013x WOS OpenAlex
Идентификаторы БД:
| Web of science: | WOS:000386165000008 |
| OpenAlex: | W2531822912 |