Atom-transfer radical addition of fluoroalkyl bromides to alkenes via a photoredox/copper catalytic system

Atom-transfer radical addition of fluoroalkyl bromides to alkenes via a photoredox/copper catalytic system Full article

Journal

Chemical Communications
ISSN: 1359-7345 , E-ISSN: 1364-548X

Output data

Year: 2021, Volume: 57, Number: 42, Pages: 5219-5222 Pages count : 4 DOI: 10.1039/d1cc01609a

Authors

Kostromitin Vladislav S. ^1,2 , Zemtsov Artem A. ¹ , Kokorekin Vladimir A. ¹ , Levin Vitalij V. ¹ , Dilman Alexander D. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Moscow 119991, Leninsky prosp. 47, Russian Federation
2	Lomonosov Moscow State University

A method for the addition of fluorinated alkyl bromides to alkenes is described. The reaction proceeds under visible light irradiation in the presence of two catalysts: Ir(ppy)3 and N-heterocyclic carbene ligated copper bromide (IMesCuBr). The role of the iridium photocatalyst is to generate the fluoralkyl radical, while the copper promotes formation of the carbon–bromine bond.

Kostromitin V.S. , Zemtsov A.A. , Kokorekin V.A. , Levin V.V. , Dilman A.D.
Atom-transfer radical addition of fluoroalkyl bromides to alkenes via a photoredox/copper catalytic system
Chemical Communications. 2021. V.57. N42. P.5219-5222. DOI: 10.1039/d1cc01609a WOS Scopus OpenAlex

Web of science:	WOS:000644966000001
Scopus:	2-s2.0-85106564686
OpenAlex:	W3158384773

DB	Citing
OpenAlex	20
Scopus	21
Web of science	17