Synthesis of 5-amino-6-nitro-1,2,3,4-tetrazine 1,3-dioxide

Synthesis of 5-amino-6-nitro-1,2,3,4-tetrazine 1,3-dioxide Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2016, Volume: 65, Number: 11, Pages: 2763-2765 Pages count : 3 DOI: 10.1007/s11172-016-1650-2

Authors

Guskov A.A. ¹ , Klenov M.S. ¹ , Churakov A.M. ¹ , Tartakovsky V.A. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation

5-Amino-(tert-butyl-NNO-azoxy)-1,2,3,4-tetrazine 1,3-dioxide reacts with nitronium tetra-fluoroborate to give 5-amino-6-nitro-1,2,3,4-tetrazine 1,3-dioxide. This compound is of interest as a new energetic material. A plausible reaction mechanism involves electrophilic substitution of the tert-butyl-NNO-azoxy group by the nitro group.

Guskov A.A. , Klenov M.S. , Churakov A.M. , Tartakovsky V.A.
Synthesis of 5-amino-6-nitro-1,2,3,4-tetrazine 1,3-dioxide
Russian Chemical Bulletin. 2016. V.65. N11. P.2763-2765. DOI: 10.1007/s11172-016-1650-2 WOS Scopus OpenAlex

≡ Web of science:	WOS:000401572700033
≡ Scopus:	2-s2.0-85019193024
≡ OpenAlex:	W2614759422