Synthesis of Tetrazino‐tetrazine 1,3,6,8‐Tetraoxide (TTTO)

Synthesis of Tetrazino‐tetrazine 1,3,6,8‐Tetraoxide (TTTO) Full article

Journal

Angewandte Chemie International Edition
ISSN: 1433-7851 , E-ISSN: 1521-3773

Output data

Year: 2016, Volume: 55, Number: 38, Pages: 11472-11475 Pages count : 4 DOI: 10.1002/anie.201605611

Authors

Klenov Michael S. ¹ , Guskov Alexey A. ¹ , Anikin Oleg V. ¹ , Churakov Aleksandr M. ¹ , Strelenko Yurii A. ¹ , Fedyanin Ivan V. ² , Lyssenko Konstantin A. ² , Tartakovsky Vladimir A. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry Russian Academy of Sciences 47 Leninsky prosp., 119991 Moscow Russian Federation
2	A. N. Nesmeyanov Institute of Organoelement Compounds Russian Academy of Sciences 28 Vavilova St., 119991 Moscow Russian Federation

This study presents the first synthesis and characterization of a new high energy compound [1,2,3,4]tetrazino[5,6-e][1,2,3,4]tetrazine 1,3,6,8-tetraoxide (TTTO). It was synthesized in ten steps from 2,2-bis(tert-butyl-NNO-azoxy)acetonitrile. The synthetic strategy was based on the sequential closure of two 1,2,3,4-tetrazine 1,3-dioxide rings by the generation of oxodiazonium ions and their intramolecular coupling with tert-butyl-NNO-azoxy groups. The TTTO structure was confirmed by single-crystal X-ray.

Klenov M.S. , Guskov A.A. , Anikin O.V. , Churakov A.M. , Strelenko Y.A. , Fedyanin I.V. , Lyssenko K.A. , Tartakovsky V.A.
Synthesis of Tetrazino‐tetrazine 1,3,6,8‐Tetraoxide (TTTO)
Angewandte Chemie International Edition. 2016. V.55. N38. P.11472-11475. DOI: 10.1002/anie.201605611 WOS Scopus OpenAlex

≡ Web of science:	WOS:000383748900026
≡ Scopus:	2-s2.0-84978827381
≡ OpenAlex:	W2484979919