Reactions of gem-Difluorinated Phosphonium Salts Induced by Light | Sciact

Reactions of gem-Difluorinated Phosphonium Salts Induced by Light Научная публикация

Журнал

Organic Letters
ISSN: 1523-7060 , E-ISSN: 1523-7052

Вых. Данные

Год: 2016, Том: 18, Номер: 5, Страницы: 996-999 Страниц : 4 DOI: 10.1021/acs.orglett.6b00117

Авторы

Panferova Liubov I. ¹ , Tsymbal Artem V. ^2,1 , Levin Vitalij V. ¹ , Struchkova Marina I. ¹ , Dilman Alexander D. ¹

Организации

1	N.D. Zelinsky Institute of Organic Chemistry, Leninsky prosp. 47, 119991 Moscow, Russian Federation
2	Department of Chemistry, Moscow State University, Leninskie Gory 1-3, 119991 Moscow, Russian Federation

gem-Difluorinated phosphonium salts, which are readily obtained from aldehydes and difluoromethylene phosphobetaine, can serve as a source of radicals under reductive conditions. An iridium complex or Hantzsch ester was used as a one-electron reducing agent when irradiated with visible light. The fluorinated radicals were trapped with various alkenes, leading to products either via a photoredox cycle (for the iridium catalyst) or via a hydrogen atom transfer (for the Hantzsch ester).

Panferova L.I. , Tsymbal A.V. , Levin V.V. , Struchkova M.I. , Dilman A.D.
Reactions of gem-Difluorinated Phosphonium Salts Induced by Light
Organic Letters. 2016. V.18. N5. P.996-999. DOI: 10.1021/acs.orglett.6b00117 Scopus OpenAlex

Scopus:	2-s2.0-84960157688
OpenAlex:	W2331899840

БД	Цитирований
OpenAlex	82
Scopus	81