13C-NMR glycosylation effects in (1→3)-linked furanosyl-pyranosides

13C-NMR glycosylation effects in (1→3)-linked furanosyl-pyranosides Full article

Journal

Carbohydrate Research
ISSN: 1873-426X , E-ISSN: 0008-6215

Output data

Year: 2015, Volume: 417, Pages: 1-10 Pages count : 10 DOI: 10.1016/j.carres.2015.08.014

Authors

Gerbst Alexey G. ¹ , Krylov Vadim B. ¹ , Vinnitskiy Dmitry Z. ¹ , Dmitrenok Andrey S. ¹ , Shashkov Alexander S. ¹ , Nifantiev Nikolay E. ¹

Affiliations

1	Laboratory of Glycoconjugate Chemistry, N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prospect 47, 119991 Moscow, Russia

Synthesis, theoretical conformational analysis (molecular mechanics and DFT calculations) and NMR spectral data including the 13C-NMR glycosylation effects for six pairs of isomeric furanosyl-(1→3)-pyranosides with different anomeric and absolute configurations of furanosyl units as well as configurations of C2 and C4 in the pyranoside units are described. The determined 13C-NMR glycosylation effects were shown to correlate with the pattern of intramolecular interactions around the inter-unit bonds.

Gerbst A.G. , Krylov V.B. , Vinnitskiy D.Z. , Dmitrenok A.S. , Shashkov A.S. , Nifantiev N.E.
13C-NMR glycosylation effects in (1→3)-linked furanosyl-pyranosides
Carbohydrate Research. 2015. V.417. P.1-10. DOI: 10.1016/j.carres.2015.08.014 WOS Scopus OpenAlex

≡ Web of science:	WOS:000364859900001
≡ Scopus:	2-s2.0-84941885367
≡ OpenAlex:	W1119501938