Oxidative C-O coupling of benzylmalononitrile with 3-(hydroxyimino)pentane-2,4-dione Научная публикация
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Russian Journal of Organic Chemistry
ISSN: 1608-3393 , E-ISSN: 1070-4280 |
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| Вых. Данные | Год: 2015, Том: 51, Номер: 1, Страницы: 10-13 Страниц : 4 DOI: 10.1134/s1070428015010029 | ||
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Реферат:
Oxidative C-O coupling of benzylmalononitrile with 3-(hydroxyimino)pentane-2,4-dione has been accomplished. This reaction is the first example of oxidative C-O coupling of a malononitrile with an oxime. The best yield (65%) of the coupling product, 2-benzyl-2-[(2,4-dioxopent-3-ylidene)aminooxy]malononitrile, has been achieved with the use of Cu(ClO4)2 · 6 H2O as oxidant. It is believed that the reaction involves intermediate formation of oxygen-centered aminoxyl radical.
Библиографическая ссылка:
Krylov I.B.
, Terent’ev A.O.
Oxidative C-O coupling of benzylmalononitrile with 3-(hydroxyimino)pentane-2,4-dione
Russian Journal of Organic Chemistry. 2015. V.51. N1. P.10-13. DOI: 10.1134/s1070428015010029 WOS Scopus OpenAlex
Oxidative C-O coupling of benzylmalononitrile with 3-(hydroxyimino)pentane-2,4-dione
Russian Journal of Organic Chemistry. 2015. V.51. N1. P.10-13. DOI: 10.1134/s1070428015010029 WOS Scopus OpenAlex
Идентификаторы БД:
| ≡ Web of science: | WOS:000349377700002 |
| ≡ Scopus: | 2-s2.0-84923170122 |
| ≡ OpenAlex: | W2029720319 |