Light-Mediated Sulfur–Boron Exchange

Light-Mediated Sulfur–Boron Exchange Full article

Journal

Organic Letters
ISSN: 1523-7060 , E-ISSN: 1523-7052

Output data

Year: 2021, Volume: 23, Number: 10, Pages: 3919-3922 Pages count : 4 DOI: 10.1021/acs.orglett.1c01080

Authors

Panferova Liubov I. ¹ , Dilman Alexander D. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Leninsky prosp. 47, 119991 Moscow, Russian Federation

Interaction of sulfides bearing a tetrafluoropyridinyl group with bis(catecholato)diboron followed by treatment with pinacol and triethylamine affording pinacol boronic esters is described. The reaction is promoted by an organic photocatalyst (3DPA2FBN) under irradiation with 400 nm light, and works with primary, secondary, and tertiary sulfides. The electron depleting character of the fluorinated pyridine fragment plays an important role in generating alkyl radicals.

Panferova L.I. , Dilman A.D.
Light-Mediated Sulfur–Boron Exchange
Organic Letters. 2021. V.23. N10. P.3919-3922. DOI: 10.1021/acs.orglett.1c01080 WOS Scopus OpenAlex

Web of science:	WOS:000656057300023
Scopus:	2-s2.0-85106479146
OpenAlex:	W3157914859

DB	Citing
OpenAlex	22
Scopus	18
Web of science	18