Dinitrofuroxan cycloreversion as a novel general approach for the synthesis of nitroazoles

Dinitrofuroxan cycloreversion as a novel general approach for the synthesis of nitroazoles Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2015, Volume: 64, Number: 2, Pages: 415-422 Pages count : 8 DOI: 10.1007/s11172-015-0878-6

Authors

Fershtat L.L. ¹ , Khakimov D.V. ¹ , Makhova N.N. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

A novel general approach towards various nitroazoles via tandem process involving dinitrofuroxan cycloreversion followed by [3+2] cycloaddition of generated in situ nitroformonitrile oxide is developed. The reaction is promoted by addition of catalytic amounts of ionic liquids. Plausible mechanisms of the described processes based on quantum chemical calculations are proposed.

Fershtat L.L. , Khakimov D.V. , Makhova N.N.
Dinitrofuroxan cycloreversion as a novel general approach for the synthesis of nitroazoles
Russian Chemical Bulletin. 2015. V.64. N2. P.415-422. DOI: 10.1007/s11172-015-0878-6 WOS Scopus OpenAlex

≡ Web of science:	WOS:000363260900022
≡ Scopus:	2-s2.0-84945174330
≡ OpenAlex:	W2334416618