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Synthesis and properties of fluorosilicon compounds for protection of cultural monuments from harmful environmental exposure Full article

Journal Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285
Output data Year: 2014, Volume: 63, Number: 2, Pages: 546-548 Pages count : 3 DOI: 10.1007/s11172-014-0467-0
Authors Yarosh A.A. 1 , Krukovsky S.P. 1 , Sakharov A.M. 1 , Popovich M.Yu 1 , Kotov V.M. 2 , Pryakhina T.A. 2
Affiliations
1 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation
2 A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

Abstract: Methods for the synthesis of perfluorocarboxylic acid derivatives with reactive trialkoxysilyl groups soluble in organic and organofluorine (1,1,2-trichlorotrif1uoroethane, etc.) solvents have been developed. The contact angles of water and decalin, water absorption, resistance to freezing, and salt-resistance of limestone and plaster samples treated with these compounds were determined. Fluorosilicon organic compounds impart more hydro- and oleophobic properties to the protected surfaces than known organosilicon agents and reliably protect sculptures and architectural monuments from mold and algae deposition.
Cite: Yarosh A.A. , Krukovsky S.P. , Sakharov A.M. , Popovich M.Y. , Kotov V.M. , Pryakhina T.A.
Synthesis and properties of fluorosilicon compounds for protection of cultural monuments from harmful environmental exposure
Russian Chemical Bulletin. 2014. V.63. N2. P.546-548. DOI: 10.1007/s11172-014-0467-0 WOS Scopus OpenAlex
Identifiers:
≡ Web of science: WOS:000343607900035
≡ Scopus: 2-s2.0-84910134578
≡ OpenAlex: W1984655083
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