Safe and Convenient Synthesis of Primary N-Nitramines in the Freon Media

Safe and Convenient Synthesis of Primary N-Nitramines in the Freon Media Full article

Journal

Synthesis
ISSN: 1437-210X , E-ISSN: 0039-7881

Output data

Year: 2016, Volume: 49, Number: 05, Pages: 1103-1108 Pages count : 6 DOI: 10.1055/s-0036-1588616

Authors

Zharkov Mikhail N. ¹ , Kuchurov Ilya V. ¹ , Fomenkov Igor V. ¹ , Tartakovsky Vladimir A. ¹ , Fedyanin Ivan V. ² , Zlotin Sergei G. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47, Leninsky prosp., 119991 Moscow, Russian Federation
2	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilova St., 119991 Moscow, Russian Federation

A convenient one-pot synthesis of primary aliphatic N-nitramines, which includes the nitration of available N,N′-dialkyloxalamides or N-alkylcarbamates with dinitrogen pentoxide in the 1,1,1,2-tetrafluoroethane media followed by ammonolysis of intermediate N-nitroamides in the same solvent has been developed. The method is environmentally safe, and affords target N-nitramines in up to 94% overall yield.

Zharkov M.N. , Kuchurov I.V. , Fomenkov I.V. , Tartakovsky V.A. , Fedyanin I.V. , Zlotin S.G.
Safe and Convenient Synthesis of Primary N-Nitramines in the Freon Media
Synthesis. 2016. V.49. N05. P.1103-1108. DOI: 10.1055/s-0036-1588616 Scopus OpenAlex

Scopus:	2-s2.0-84991280268
OpenAlex:	W2531067913

DB	Citing
OpenAlex	18
Scopus	18