Electrooxidation of potassium hepta(methoxycarbonyl)cycloheptatrienide in acetonitrile

Electrooxidation of potassium hepta(methoxycarbonyl)cycloheptatrienide in acetonitrile Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2014, Volume: 24, Number: 6, Pages: 363-364 Pages count : 2 DOI: 10.1016/j.mencom.2014.11.018

Authors

Kokorekin Vladimir A. ¹ , Yanilkin Vitaliy V. ² , Morozov Vladimir I. ² , Tomilov Yury V. ¹ , Platonov Dmitry N. ¹ , Petrosyan Vladimir A. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
2	A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, 420088 Kazan, Russian Federation

The quasi-reversible one-electron electrooxidation of the 1,2,3,4,5,6,7-hepta(methoxy-carbonyl)cycloheptatrienide anion in MeCN at 22 °C gives a radical whose ESR spectrum consists of seven lines with splittings from six protons with an intensity ratio of 1: 6: 15: 20: 15: 6: 1, which likely corresponds to a substituted bicyclo[3.2.0]heptadienyl structure.

Kokorekin V.A. , Yanilkin V.V. , Morozov V.I. , Tomilov Y.V. , Platonov D.N. , Petrosyan V.A.
Electrooxidation of potassium hepta(methoxycarbonyl)cycloheptatrienide in acetonitrile
Mendeleev Communications. 2014. V.24. N6. P.363-364. DOI: 10.1016/j.mencom.2014.11.018 WOS Scopus OpenAlex

≡ Web of science:	WOS:000347139100018
≡ Scopus:	2-s2.0-84911861724
≡ OpenAlex:	W2032032824