Synthesis and adsorption properties of new calcium metal-organic framework (Ca-MOF) ZIOC-10 based on a new carbazole linker

Synthesis and adsorption properties of new calcium metal-organic framework (Ca-MOF) ZIOC-10 based on a new carbazole linker Научная публикация

Журнал

Microporous and Mesoporous Materials
ISSN: 1873-3093 , E-ISSN: 1387-1811

Вых. Данные

Год: 2024, Том: 373, Номер статьи : 113120, Страниц : DOI: 10.1016/j.micromeso.2024.113120

Авторы

Deyko G.S. ¹ , Kravtsov L.A. ¹ , Glukhov L.M. ¹ , Davshan N.A. ¹ , Kalmykov K.B. ² , Chernyshev V.V. ² , Murashova E.V. ² , Kustov L.M. ^2,1

Организации

1	Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prospekt 47, Moscow, 119991, Russia
2	Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory 1-3, Moscow, 119991, Russia

A carbazole-based linker 9-(carboxymethyl)carbazole-3,6-dicarboxylic acid (H3cbzac) was synthesized for the first time. Its structure was confirmed via 1H NMR and Powder X-Ray Diffraction (PXRD) methods. A novel calcium-based 2D MOF Ca(H2cbzac)2(DMF)2 (ZIOC-10) was synthesized via a solvothermal procedure. It was found that the obtained framework undergoes several structural changes upon heating, which lead to the formation of a new framework Ca(H2cbzac)2 (ZIOC-10a). Noteworthy, ZIOC-10 transforms into the permanent porous (524 m2/g) 3D framework, which can absorb methane, ethane, propane, and carbon dioxide at room temperature.

Deyko G.S. , Kravtsov L.A. , Glukhov L.M. , Davshan N.A. , Kalmykov K.B. , Chernyshev V.V. , Murashova E.V. , Kustov L.M.
Synthesis and adsorption properties of new calcium metal-organic framework (Ca-MOF) ZIOC-10 based on a new carbazole linker
Microporous and Mesoporous Materials. 2024. V.373. 113120 . DOI: 10.1016/j.micromeso.2024.113120 WOS Scopus OpenAlex

Web of science:	WOS:001231749600001
Scopus:	2-s2.0-85190353011
OpenAlex:	W4394823105

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