Co‐Catalyzed Peroxidation of Cyclic β‐Dicarbonyls

Co‐Catalyzed Peroxidation of Cyclic β‐Dicarbonyls Full article

Journal

European Journal of Organic Chemistry
ISSN: 1434-193X , E-ISSN: 1099-0690

Output data

Year: 2024, Volume: 27, Number: 13, Article number : e202400078, Pages count : DOI: 10.1002/ejoc.202400078

Authors

Bityukov Oleg V. ¹ , Serdyuchenko Pavel Yu. ¹ , Vil’ Vera A. ¹ , Nikishin Gennady I. ¹ , He Liang-Nian ² , Terent'ev Alexander O. ¹

Affiliations

1	Zelinsky Institute of Organic Chemistry RAS Laboratory for Studies of Homolytic Reactions RUSSIAN FEDERATION
2	Nankai University State Key Laboratory and Institute of Elemento-Organic Chemistry CHINA

The reactivity of cyclic β-dicarbonyls (cyclic β-diketones, 4-hydroxy-2(5H)-furanones, and Meldrum‘s acids) towards metal/hydroperoxide system was disclosed. An efficient method for the peroxidation of 4-hydroxy-2(5H)-furanones and Meldrum's acids with TBHP has been developed using Co2+ salt as a catalyst. Cycle cleavage, expected from previous reports for cyclic β-dicarbonyls, was observed only for cyclic 1,3-diketones. Overall, this work extends the understanding of metal-catalyzed peroxidation towards different structural motifs.

Bityukov O.V. , Serdyuchenko P.Y. , Vil’ V.A. , Nikishin G.I. , He L-N. , Terent'ev A.O.
Co‐Catalyzed Peroxidation of Cyclic β‐Dicarbonyls
European Journal of Organic Chemistry. 2024. V.27. N13. e202400078 . DOI: 10.1002/ejoc.202400078 WOS Scopus OpenAlex

Web of science:	WOS:001187732900001
Scopus:	2-s2.0-85188179123
OpenAlex:	W4392374608

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