Mechanism of the anodic dissolution of gold in solutions of 6-alkyl-1,5-diazabicyclo[3.1.0]hexanes

Mechanism of the anodic dissolution of gold in solutions of 6-alkyl-1,5-diazabicyclo[3.1.0]hexanes Full article

Journal

Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X

Output data

Year: 2016, Volume: 90, Number: 9, Pages: 1903-1908 Pages count : 6 DOI: 10.1134/s0036024416090284

Authors

Vedenyapina M.D. ^1,2 , Kuznetsov V.V. ¹ , Makhova N.N. ¹ , Vedenyapin A.A. ^1,2

Affiliations

1	Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia
2	Moscow Technological Institute, Moscow, 119334 Russia

The electrochemical corrosion of gold in solutions of 6,6-dimethyl-1,5-diazabicyclo[3.1.0]hexane (I) and 6-methyl-1,5-diazabicyclo[3.1.0]hexane (II) on a gold electrode is studied via cyclic voltammetry. It is shown that the galvanostatic electrolysis of weakly basic aqueous solutions of I and II on gold anodes results in the corrosion of Au electrodes, probably with the formation of organic complexes of gold that are reduced to form a gold mirror on the inner surface of an electrochemical cell during electrolysis. A mechanism is proposed for the investigated processes.

Vedenyapina M.D. , Kuznetsov V.V. , Makhova N.N. , Vedenyapin A.A.
Mechanism of the anodic dissolution of gold in solutions of 6-alkyl-1,5-diazabicyclo[3.1.0]hexanes
Russian Journal of Physical Chemistry A. 2016. V.90. N9. P.1903-1908. DOI: 10.1134/s0036024416090284 WOS Scopus OpenAlex

Web of science:	WOS:000385283500032
Scopus:	2-s2.0-84982199296
OpenAlex:	W2482254873

DB	Citing
OpenAlex	9
Scopus	9
Web of science	9