Реферат: Catalytic properties of Pd—Cu bimetallic catalysts supported on SiO2 and Al2O3 were studied in a model reaction of selective hydrogenation of diphenylacetylene. Application of PdCu2(AcO)6 heterobimetallic acetate complex as a precursor made it possible to obtain homogeneous Pd—Cu bimetallic nanoparticles. This result was supported by the data of IR spectroscopy of adsorbed CO. The Pd-Cu catalysts showed considerably higher selectivity than monometallic samples. Moreover, the introduction of copper decreases the hydrogenation rate of diphenylethylene (DPE) to diphenylethane. As a result, the maximum yield of the target product, DPE, increased from 78 to 93% in the presence of Pd—Cu catalysts.

Библиографическая ссылка: Mashkovsky I.S. , Markov P.V. , Bragina G.O. , Tkachenko O.P. , Yakushev I.A. , Kozitsyna N.Y. , Vargaftik M.N. , Stakheev A.Y.
Highly selective catalysts for liquid-phase hydrogenation of substituted alkynes based on Pd—Cu bimetallic nanoparticles
Russian Chemical Bulletin. 2016. V.65. N2. P.425-431. DOI: 10.1007/s11172-016-1316-0 WOS Scopus OpenAlex

Идентификаторы БД:

Web of science:	WOS:000387600700011
Scopus:	2-s2.0-85013800162
OpenAlex:	W2553043503

Цитирование в БД:

БД	Цитирований
OpenAlex	8
Scopus	8
Web of science	7

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