Kinetic and thermodynamic parameters of hydrogen release during the heterogeneous catalytic dehydrogenation of cis- and trans-isomers of perhydro-m-terphenyl

Kinetic and thermodynamic parameters of hydrogen release during the heterogeneous catalytic dehydrogenation of cis- and trans-isomers of perhydro-m-terphenyl Научная публикация

Журнал

Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X

Вых. Данные

Год: 2016, Том: 90, Номер: 10, Страницы: 1921-1924 Страниц : 4 DOI: 10.1134/s0036024416100162

Авторы

Kalenchuk A.N. ^1,2 , Bogorodskii S.E. ³ , Bogdan V.I. ^1,2

Организации

1	Department of Chemistry, Moscow State University, Moscow, 119991 Russia
2	Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991 Russia
3	Advanced Laser Technologies Division, Institute of Laser and Information Technologies, Russian Academy of Sciences, Troitsk, Moscow oblast, 142092 Russia

Comparative studies on the temperature dependence of the dehydrogenation of cis- and trans-isomers of perhydro-m-terphenyl are performed in a flow catalytic reactor. Rate constants and equilibrium constants of all elementary acts of this reaction are calculated on basis of experimental data using the KINET 0.8 program for the mathematical modeling of the kinetics of complex reactions. The resulting data indicate that perhydro-m-terphenyl cis- and trans-isomers structural differences have no appreciable effect on dehydrogenation.

Kalenchuk A.N. , Bogorodskii S.E. , Bogdan V.I.
Kinetic and thermodynamic parameters of hydrogen release during the heterogeneous catalytic dehydrogenation of cis- and trans-isomers of perhydro-m-terphenyl
Russian Journal of Physical Chemistry A. 2016. V.90. N10. P.1921-1924. DOI: 10.1134/s0036024416100162 WOS Scopus OpenAlex

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