Novel Melt‐Castable Energetic Pyrazole: A Pyrazolyl‐Furazan Framework Bearing Five Nitro Groups

Novel Melt‐Castable Energetic Pyrazole: A Pyrazolyl‐Furazan Framework Bearing Five Nitro Groups Full article

Journal

Propellants, Explosives, Pyrotechnics
ISSN: 0721-3115 , E-ISSN: 1521-4087

Output data

Year: 2016, Volume: 41, Number: 5, Pages: 789-792 Pages count : 4 DOI: 10.1002/prep.201600050

Authors

Dalinger Igor L. ¹ , Suponitsky Kyrill Yu. ² , Pivkina Alla N. ^3,4 , Sheremetev Aleksei B. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 LeninskyProsp., Moscow, 119991 Russian Federation
2	A. N. Nesmeyanov Institute of OrganoelementCompounds, Russian Academy of Sciences, 28 Vavilov St., Moscow, 119991 Russian Federation
3	N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 Kosyginast., Moscow, 117977 Russian Federation
4	National Research Nuclear University MEPhI, 31 Kashirskoehighway, Moscow, 115409 Russian Federation

Continuing advances in energetic pyrazole construction foster further its rational use. This work establishes an approach for the first synthesis of nitropyrazole that bear both furazan and trinitromethyl moieties. The approach to the installation of the C(NO2)3 group exploits the destructive nitration of N-acetonyl group. The target 3-(3,4-dinitro-1-(trinitromethyl)-1H-pyrazol-5-yl)-4-methylfurazan (6) has promising explosive properties.

Dalinger I.L. , Suponitsky K.Y. , Pivkina A.N. , Sheremetev A.B.
Novel Melt‐Castable Energetic Pyrazole: A Pyrazolyl‐Furazan Framework Bearing Five Nitro Groups
Propellants, Explosives, Pyrotechnics. 2016. V.41. N5. P.789-792. DOI: 10.1002/prep.201600050 WOS Scopus OpenAlex

≡ Web of science:	WOS:000385829600003
≡ Scopus:	2-s2.0-84991406680
≡ OpenAlex:	W2531691526