Kinetics and mechanism of the anodic dissolution of gold in solutions of 1,5-diazabicyclo[3.1.0]hexane and its precursors

Kinetics and mechanism of the anodic dissolution of gold in solutions of 1,5-diazabicyclo[3.1.0]hexane and its precursors Научная публикация

Журнал

Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X

Вых. Данные

Год: 2014, Том: 88, Номер: 2, Страницы: 331-337 Страниц : 7 DOI: 10.1134/s0036024414020241

Авторы

Simakova A.P. ¹ , Vedenyapina M.D. ¹ , Kuznetsov V.V. ¹ , Makhova N.N. ¹ , Vedenyapin A.A. ¹

Организации

1	Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

Studies of the electrochemical behavior of hexahydropyrimidine, 1,5-diazabicyclo[3.1.0]hexane, and 1,3-diaminopropane on a gold electrode via cyclic voltammetry allow us to conclude that gold anodes are subject to corrosion in presence these compounds, yielding complexes that migrate into the solutions and discharge on the counter electrode, producing gold metal deposit. 1,5-Diazabicyclo[3.1.0]hexane is found to form complexes with gold that are much more stable that those formed by hexahydropyrimidine and 1,3-diaminopropane.

Simakova A.P. , Vedenyapina M.D. , Kuznetsov V.V. , Makhova N.N. , Vedenyapin A.A.
Kinetics and mechanism of the anodic dissolution of gold in solutions of 1,5-diazabicyclo[3.1.0]hexane and its precursors
Russian Journal of Physical Chemistry A. 2014. V.88. N2. P.331-337. DOI: 10.1134/s0036024414020241 WOS Scopus OpenAlex

≡ Web of science:	WOS:000329253800024
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