Alkylation of 1-alkoxy-3-methyl-1-triazene 2-oxide sodium salts

Alkylation of 1-alkoxy-3-methyl-1-triazene 2-oxide sodium salts Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2015, Volume: 64, Number: 12, Pages: 2851-2856 Pages count : 6 DOI: 10.1007/s11172-015-1237-3

Authors

Smirnov G.A. ¹ , Gordeev P.B. ¹ , Nikitin S.V. ¹ , Pokhvisneva G.V. ¹ , Strelenko Yu.A. ¹ , Ternikova T.V. ¹ , Luk´yanov O.A. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

1-Alkoxy-3-methyl-1-triazene 2-oxide sodium salts react with chloromethyl methyl sulfide to give a mixture of 1-alkoxy-3-methyl-3-(methylthiomethyl)-1-triazene 2-oxides and 3-alkoxy-1-methyl-3-(methylthiomethyl)-1-triazene 2-oxides. The reaction of these triazene oxide sodium salts with 3,3-dialkyl-1-chloromethoxy-1-triazene 2-oxides produces a complex mixture of product bearing the oxytriazene moieties of the starting alkoxy-1-triazene 2-oxides bonded with the methylene group as a key structural fragment.

Smirnov G.A. , Gordeev P.B. , Nikitin S.V. , Pokhvisneva G.V. , Strelenko Y.A. , Ternikova T.V. , Luk´yanov O.A.
Alkylation of 1-alkoxy-3-methyl-1-triazene 2-oxide sodium salts
Russian Chemical Bulletin. 2015. V.64. N12. P.2851-2856. DOI: 10.1007/s11172-015-1237-3 WOS Scopus OpenAlex

≡ Web of science:	WOS:000383864900018
≡ Scopus:	2-s2.0-84988407760
≡ OpenAlex:	W2519104897