Anionic coordination copolymerization of propylene oxide, carbon dioxide, and l-lactide

Anionic coordination copolymerization of propylene oxide, carbon dioxide, and l-lactide Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2015, Volume: 64, Number: 12, Pages: 2914-2918 Pages count : 5 DOI: 10.1007/s11172-015-1247-1

Authors

Nysenko Z.N. ¹ , Said-Galiev E.E. ² , Ilyin M.M. ² , Rusak V.V. ¹ , Glazkov A.A. ¹ , Sakharov A.M. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation
2	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilova str., Moscow, 119991, Russian Federation

Terpolymers with various L-lactic acid content in the polypropylene carbonate chain were synthesized by copolymerization of carbon dioxide, propylene oxide, and L-lactide. Zinc adipate was used as a catalyst. Terpolymerization products were characterized by 1H and 13C NMR, 2D {1Н—13С} HMBC, IR spectroscopy, and gel-permeation chromatography. The influence of monomer molar ratio, temperature, and reaction duration on the composition and molecular-mass characteristics of terpolymers was studied. A few questions of terpolymerization mechanism were discussed.

Nysenko Z.N. , Said-Galiev E.E. , Ilyin M.M. , Rusak V.V. , Glazkov A.A. , Sakharov A.M.
Anionic coordination copolymerization of propylene oxide, carbon dioxide, and l-lactide
Russian Chemical Bulletin. 2015. V.64. N12. P.2914-2918. DOI: 10.1007/s11172-015-1247-1 WOS Scopus OpenAlex

≡ Web of science:	WOS:000383864900028
≡ Scopus:	2-s2.0-84988421974
≡ OpenAlex:	W2520350605