Synthesis of functionalized triethylgermyl-containing phosphinic acids

Synthesis of functionalized triethylgermyl-containing phosphinic acids Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2023, Volume: 72, Pages: 2979–2986 Pages count : DOI: 10.1007/s11172-023-4109-2

Authors

Prishchenko A.A. ¹ , Livantsov M.V. ¹ , Novikova O.P. ¹ , Livantsova L.I. ¹ , Baranin S.V. ² , Bubnov Yu.N ^2,3

Affiliations

1	M. V. Lomonosov Moscow State University, Chemical Department, Build. 3, 1 Leninskiye Gory, 119991 Moscow, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation
3	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Build. 1, 28 ul. Vavilova, 119991 Moscow, Russian Federation

Convenient syntheses of functionalized phosphonous and phosphinic acids containing hydrolysis-resistant triethylgermyl moieties have been developed. Radical addition of bis(trimethylsiloxy)phosphine to (triethyl)(vinyl)germane occurs regioselectively to give novel germanium-containing ethylphosphonites, the subsequent functionalization of which affords various target acids. The resulting compounds are of interest as promising biologically active substances and water-soluble ligands.

Prishchenko A.A. , Livantsov M.V. , Novikova O.P. , Livantsova L.I. , Baranin S.V. , Bubnov Y.N.
Synthesis of functionalized triethylgermyl-containing phosphinic acids
Russian Chemical Bulletin. 2023. V.72. P.2979–2986. DOI: 10.1007/s11172-023-4109-2 WOS Scopus OpenAlex

≡ Web of science:	WOS:001154671000028
≡ Scopus:	2-s2.0-85183661756
≡ OpenAlex:	W4391391094