Unexpected formation of (trinitromethyl)pyrazines

Unexpected formation of (trinitromethyl)pyrazines Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2015, Volume: 25, Number: 3, Pages: 193-195 Pages count : 3 DOI: 10.1016/j.mencom.2015.05.011

Authors

Yudin Igor L. ¹ , Palysaeva Nadezhda V. ¹ , Averkiev Boris B. ² , Sheremetev Aleksei B. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
2	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991 Moscow, Russian Federation

Treatment of 2-alkoxy-3-methylpyrazines with HNO3 /H2SO4 induces an unusual reaction accompanied by the methyl group nitration with the formation of (trinitromethyl)pyrazines, a structural motif previously unknown in diazine family.

Yudin I.L. , Palysaeva N.V. , Averkiev B.B. , Sheremetev A.B.
Unexpected formation of (trinitromethyl)pyrazines
Mendeleev Communications. 2015. V.25. N3. P.193-195. DOI: 10.1016/j.mencom.2015.05.011 WOS Scopus OpenAlex

≡ Web of science:	WOS:000357142000011
≡ Scopus:	2-s2.0-84930939122
≡ OpenAlex:	W1044001209