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Sulfones Bearing Perfluorinated Pyridine Group: Synthesis and Photocatalytic Reaction with α‐(Trifluoromethyl)styrenes Научная публикация

Журнал Chemcatchem
ISSN: 1867-3899 , E-ISSN: 1867-3880
Вых. Данные Год: 2023, Том: 15, Номер: 12, Номер статьи : e202300505, Страниц : DOI: 10.1002/cctc.202300505
Авторы Savchenko Artem G. 1,2 , Zubkov Mikhail O. 2 , Kokorekin Vladimir A. 2 , Hu Jinbo 3 , Dilman Alexander 2
Организации
1 Department of Chemistry Moscow State University 119991 Moscow Leninskie Gory 1–3 Russian Federation
2 N. D. Zelinsky Institute of Organic Chemistry 119991 Moscow Leninsky prosp. 47 Russian Federation
3 Key Laboratory of Organofluorine Chemistry Center for Excellence in Molecular Synthesis Shanghai Institute of Organic Chemistry University of Chinese Academy of Sciences Chinese Academy of Sciences 200032 Shanghai 345 Ling-Ling Road China

Реферат: A photocatalytic protocol for the reductive coupling of tetrafluoropyridyl-substituted sulfones with α-(trifluoromethyl)styrenes in the presence of zinc and sodium iodide is reported. Sulfones were obtained by oxidation of the corresponding sulfides catalyzed by molybdenum or ruthenium salts. A combination of sulfonyl fragment and electron depleting fluorinated pyridyl group is a key feature determined properties of these sulfones. Their propensity to undergo single electron reduction and to form electron donor-acceptor complexes with N-arylamines were evaluated. Plausible pathways of fragmentation of radical anion generated after single electron reduction of sulfones were analyzed, and the pathway leading to the formation of the alkyl radical and the sulfinate anion was found preferable.
Библиографическая ссылка: Savchenko A.G. , Zubkov M.O. , Kokorekin V.A. , Hu J. , Dilman A.
Sulfones Bearing Perfluorinated Pyridine Group: Synthesis and Photocatalytic Reaction with α‐(Trifluoromethyl)styrenes
Chemcatchem. 2023. V.15. N12. e202300505 . DOI: 10.1002/cctc.202300505 WOS Scopus OpenAlex
Идентификаторы БД:
Web of science: WOS:000988864600001
Scopus: 2-s2.0-85159450960
OpenAlex: W4367312512
Цитирование в БД:
БД Цитирований
OpenAlex 9
Scopus 7
Web of science 8
Альметрики: