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Preparation, characterization, and catalytic testing of different Me–chitosan complexes for triglycerides transesterification Full article

Journal Research on Chemical Intermediates
ISSN: 0922-6168 , E-ISSN: 1568-5675
Output data Year: 2016, Volume: 42, Number: 5, Pages: 4907-4920 Pages count : 14 DOI: 10.1007/s11164-015-2330-9
Authors Finashina E.D. 1 , Kramareva N.V. 1 , Kucherov A.V. 1 , Tkachenko O.P. 1 , Kustov L.M. 1
Affiliations
1 Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prospect 47, Moscow, Russia

Abstract: A number of homogeneous and heterogenized chitosan complexes with different metals (Zn, Co, Ca, Ni, Sn, Pb) were synthesized and tested as catalysts in the reaction of transesterification of tributyrin simulating the process of biodiesel production from renewable natural feedstock (triglycerides, vegetable oils). It is found that chitosan complexes are effective catalysts for transformation of tributyrin into the corresponding esters. The comparative analysis of Me–chitosan (homogeneous), Me–chitosan (heterogeneous) and Me–chitosan/SiO2 catalysts testify that the efficiency of three-component egg-shell systems is close to that of homogeneous catalysts.
Cite: Finashina E.D. , Kramareva N.V. , Kucherov A.V. , Tkachenko O.P. , Kustov L.M.
Preparation, characterization, and catalytic testing of different Me–chitosan complexes for triglycerides transesterification
Research on Chemical Intermediates. 2016. V.42. N5. P.4907-4920. DOI: 10.1007/s11164-015-2330-9 WOS Scopus OpenAlex
Identifiers:
Web of science: WOS:000373617700062
Scopus: 2-s2.0-84974827246
OpenAlex: W1963049796
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Scopus 6
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