Protolytic and complexation properties of the cyclic thiosemicarbazone ligand

Protolytic and complexation properties of the cyclic thiosemicarbazone ligand Full article

Journal

Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350

Output data

Year: 2015, Volume: 85, Number: 1, Pages: 92-96 Pages count : 5 DOI: 10.1134/s1070363215010168

Authors

Popov L.D. ¹ , Gazieva G.A. ² , Kravchenko A.N. ² , Tkachenko Yu.N. ¹ , Askalepova O.I. ¹ , Levchenkov S.I. ³ , Karpova T.B. ² , Tupolova Yu.P. ¹ , Kogan V.A. ¹

Affiliations

1	Chemical Department, Southern Federal University, Rostov-on-Don, Russia
2	Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia
3	Southern Scientific Center of the Russian Academy of Sciences, ul. Chekhova 41, Rostov-on-Don, 344022, Russia

The acid-base properties of the thiourea based cyclic thiosemicarbazone have been studied. The tautomerism and complex formation ability of the thiosemicarbazone were investigated by the methods of quantum chemistry and electronic spectroscopy. The complexes of copper(II), nickel(II), cobalt(II), and mercury(II) were synthesized and their structure suggested.

Popov L.D. , Gazieva G.A. , Kravchenko A.N. , Tkachenko Y.N. , Askalepova O.I. , Levchenkov S.I. , Karpova T.B. , Tupolova Y.P. , Kogan V.A.
Protolytic and complexation properties of the cyclic thiosemicarbazone ligand
Russian Journal of General Chemistry. 2015. V.85. N1. P.92-96. DOI: 10.1134/s1070363215010168 WOS Scopus OpenAlex

≡ Web of science:	WOS:000349985400016
≡ Scopus:	2-s2.0-84923371793
≡ OpenAlex:	W1973512317